The second semi-final took place 2 days after the first. The only returning competitor was former winner Charlotte Perrelli who had won as Charlotte Nilsson in 1999. The top 9 in the televoting qualified automatically as with the first semi - but this time the jury pick wasn't the song that finished 10th - but the one that finished 12th in the televoting...and was our returnee from Sweden. The 10 qualifiers were Ukraine, Portugal, Croatia, Denmark, Georgia, Latvia, Turkey, Iceland, Albania & Sweden. Portugal and Iceland both qualified from the semi-final for the first time since the system was introduced in 2004.

1. (4) Ukraine - Shady Lady - Ani Lorak - 152 pts
2. (19) Portugal - Senhora do mar - Vânia Fernandes - 120 pts
3. (11) Croatia - Romanca - Kralijevi Ulice & 75 Cent - 112 pts
(13) Denmark - All Night Long - Simon Mathew - 112 pts
5. (14) Georgia - Peace Will Come - Diana Gurtskaya - 107 pts
6. (10) Latvia - Wolves Of The Sea - Pirates Of The Sea - 86 pts
7. (3) Turkey - Deli - Mor ve Ötesi - 85 pts
8. (1) Iceland - This Is My Life - Euroband - 68 pts
9. (6) Albania - Zemrën e lamë peng - Olta Boka - 67 pts
10. (18 ) Macedonia - Let Me Love You - Tamara, Vrčak & Adrijan - 64 pts
11. (12) Bulgaria - DJ, Take Me Away - Deep Zone & Balthazar - 56 pts
12. (2) Sweden - Hero - Charlotte Perrelli - 54 pts
13. (7) Switzerland - Era stupendo - Paolo Meneguzzi - 47 pts
14. (16) Malta - Vodka - Morena - 38 pts
15. (17) Cyprus - Femme fatale - Evdokia Kadi - 37 pts
16. (5) Lithuania - Nomads In The Night - Jeronimus Milus - 30 pts
17. (9) Belarus - Hasta la vista - Ruslan Alehno - 27 pts
18. (8 ) Czech Republic - Have Some Fun - Tereza Kerndlova - 9 pts
19. (15) Hungary - Candlelight - Csézy - 6 pts